Use of inverse gas chromatography to quantify interactions in amine cured epoxy resins

Flory–Huggins interaction parameters, λ, were determined for a series of probes in an amine cured epoxy resin matrix (433–493 K) and its precursors (324–363 K) by inverse gas chromatography (IGC). Hildebrand–Scatchard theory was combined with Flory–Huggins theory in order to estimate infinte dilution solubility parameters (δ₂) for the matrix and its precursors at 298 K. It was shown that the value of the solubility parameter for the cured resin matrix lies between those of its precursors. Compared to the majority of published work, an unusual aspect of this application of IGC is that solubility parameters have been determined when the stationery phases are (i) small molecules and (ii) a highly crosslinked polymer. Moreover, all possible attempts have been made to ensure equilibrium conditions between probe and stationary phase, and compensation for asymmetry of peak profile has been applied in determining δ₂. The solubility parameters estimated by IGC are in good agreement with those calculated by other methods.     

On the curing of a vinylester-urethane hybrid resin

Curing kinetics of a vinylester-urethane hybrid (VEUH) resin consisting of vinylester resin (VE) diluted in styrene and novolac type polyisocyanate (NPI) have been studied by differential scanning calorimetry (DSC). As VEUH is crosslinked via free radical polymerisation between the vinyl functions of styrene and VE, and polyaddition reaction between the secondary -OH groups of VE and -NCO of NPI, it was necessary to study these reactions separately. This was achieved by studying the curing with and without incorporating the NPI. The curing reaction was monitored by measuring the heat of reaction under isothermal and dynamic temperature conditions. Models describing the curing were developed, which are in good agreement with the experiments. A comparison between the curing of the VEUH and the VE resin without NPI leads to the conclusion that the curing of the VEUH as accessed by DSC is dominated by the radical polymerisation of styrene with VE although the two reactions are not time separated.     

新型难燃输送带胶粘剂的研制

以改性氯丁橡胶为主料、多异氰酸酯为固化剂制成的新型难燃输送带胶粘剂,具有粘接强度高、耐热性好、干燥时间短、难燃等特点,在常温常压下粘接输送带接头,固化30min即可负荷运行。     

双酚A型环氧树脂阳离子紫外光固化动力学的研究

以双酚A型环氧树脂为主体成分构成紫外阳离子光固化体系，用常规的最低光固化速度测试方法和实时傅立叶变换红外光谱法研究了各种条件对体系光固化速度的影响。结果表明，光引发剂的种类和浓度可以有效地改变光固化速度，环氧稀释剂会大幅度降低光固化速度，而羟基化合物的加入只是轻微降低光固化速度。在三元体系中，其光固化速度并不是几种作用的简单叠加，而是更加类似于羟基化合物的性质。使得通过调节合适的组分构成和配合，能够获得具有合适光固化速度的紫外阳离子光固化配方，从而会大大扩展其应用的技术领域。     

Development of sealing compositions with nanostructure iron-based fillers

The possibility of utilizing nanopowders of iron and Fe-Co-Ni produced bu a thermochemical method in the fabrication of sealing composition materials is investigated. It is established that such hermetic sealing composition materials function reliably under extremal conditions and guarantee elevated strength of adhesion to the surface of the metal and high corrosion and temperature stability. __________ Translated from Poroshkaya Metallurgiya, Nos. 3–4(448), pp. 112–117, March–April, 2006.     

MBS树脂改性PVC的研究

研究了不同类型及用量的MBS树脂对PVC抗冲击性、光学性能、拉伸性能及加工塑化性能的改性效果以及加工条件等因素的影响。结果表明 :在低用量条件下 ,随MBS树脂含量增加 ,MBS/PVC抗冲击性能有所提高 ,光学性能略有下降。此外 ,MBS/PVC制品的拉伸性能和加工性能受MBS树脂类型及用量影响不大。     

水乳型丙烯酸酯建筑防水胶的研制(Ⅱ)

摘 要 研究水乳型丙烯酸酯建筑防水胶与水泥的配比及共混性能、共混固化物胶膜的力学性能、耐冷热性能及老化性能。     

异丁烷与丁烯在炭化树脂负载PW_(12)催化剂上的烷基化

探讨了炭化树脂负载杂多酸PW1 2 催化剂制备的适宜条件 ,反应工艺条件对催化剂催化异丁烷与丁烯烷基化反应及产物分布的影响 ,分析了催化剂具有较高活性的原因 ,进行了催化剂稳定性实验。并与其它类固体酸催化剂进行了对比。     

耐高温绝缘GFRP管的真空辅助树脂传递成型工艺研究

阐述了耐高温绝缘GFRP管的成型工艺及原材料选择，并对影响成型工艺的主要因素作了理论分析及试验验证。研究表明，以TDE－85／DDS体系为为基体，以无碱无捻玻璃纤维方格布为增强材料，用VARTM工艺成型的石油勘探高性能平衡管完全满足技术要求。     

瓦楞纸板用抗水淀粉胶配方及性能研究

简要分析了玉米淀粉胶的组成及对其质量的影响，重点对粘合剂的防水性进行了研究，叙述了瓦楞纸板用抗水粘合剂的配制及工艺过程，并与常规方法制备的粘合剂进行了性能比较，测定了抗水时间，得出了瓦楞纸板用抗水粘合剂的最佳配制比例。